A Double-Cavity-Containing Porphyrin Host as a Highly Stable Epoxidation Catalyst
نویسندگان
چکیده
منابع مشابه
Covalent immobilization of the Jacobsen catalyst on mesoporous phenolic polymer: a highly enantioselective and stable asymmetric epoxidation catalyst
The Jacobsen catalyst, N,N'-bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminomanganese (III) chloride is covalently immobilized on mesoporous phenolic resin through a direct and simple procedure. The immobilization is evident from nitrogen sorption and quantitative XRF measurements. A complex loading of 0.09 mmol/g is obtained, corresponding to well dispersed Mn-complexes on the surface...
متن کاملElectron deficient nonplanar β-octachlorovanadylporphyrin as a highly efficient and selective epoxidation catalyst for olefins.
We have synthesized 2,3,7,8,12,13,17,18-octachloro-meso-tetraphenylporphyrinatooxidovanadium(iv) (VOTPPCl8) and characterized by various spectroscopic (UV-Vis, IR and EPR) techniques, MALDI-TOF mass spectrometry and elemental analysis. The DFT optimized structure of VOTPPCl8 in CH3CN exhibited a highly nonplanar saddle shape conformation of the porphyrin macrocycle. The cyclic voltammogram of V...
متن کاملHighly negative homotropic allosteric binding of viologens in a double-cavity porphyrin.
The synthesis of a double-cavity porphyrin with interesting allosteric binding properties toward viologens (N,N'-disubstituted 4,4'-bipyridines) is described. The porphyrin host forms very strong 1:2 complexes with viologens, displaying a negative allosteric behavior. The first viologen guest binds exceptionally tight (K > 107 M-1), and the second guest binds much more weakly (DeltaDeltaG = 9-1...
متن کاملA unique binaphthyl strapped iron-porphyrin catalyst for the enantioselective epoxidation of terminal olefins.
A new chiral binaphthyl-strapped iron-porphyrin 4 b that exhibits unprecedented catalytic activity toward the enantioselective epoxidation of terminal olefins was synthesized. Typical enantiomeric excesses (ee) of 90 % were measured with a maximum of 97 % for the epoxidation of styrene, whereas the turnover numbers (TON) averaged 16000.
متن کاملMagnetic nanoparticles containing Manganese salophen complex as an selective and recyclable catalyst for epoxidation of alkenes
A magnetically recoverable catalyst consisting of Mn (III) salophen complex was prepared. The synthesized catalyst was characterized by X-ray powder diffraction (XRD), transmission electron microscopy (TEM), vibrating sample magnetometry (VSM), inductively coupled plasma atomic emission spectroscopy (ICP-AES) and Fourier transform infrared (FT-IR). The immobilized catalyst was shown to be an ef...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: European Journal of Organic Chemistry
سال: 2015
ISSN: 1434-193X
DOI: 10.1002/ejoc.201500492